A Series of Two-coordinate Group-15 Element (P, As, Sb, Bi) Centered Radicals Having Bulky Alkyl Groups
Cleavage of Two Hydrogen Molecules by Boryldisilenes
Synthesis and Functionalization of a 1,2-Bis(trimethylsilyl)-1,2-disilacyclohexene That Can Serve as a Unit of cis-1,2-Dialkyldisilene
Synthesis and Functionalization of a 1,4-Bis(trimethylsilyl)tetrasila-1,3-diene through the Selective Cleavage of Si(sp2)–Si(sp3) Bonds under Mild Reaction Conditions
Structural Change upon One-Electron Reduction of an Isolable Dialkylsilylene
Facile synthesis and bridgehead-functionalization of bicyclo[3.3.3]pentasiloxanes
Stable Push-Pull Disilene: Substantial Donor-Acceptor Interactions through the Si=Si Double Bond
Benzodisilacyclobutadienes: 8π-Electron Systems with An Antiaromatic Silicon Ring
Heteroaryldisilenes: heteroaryl groups serve as electron acceptors for Si=Si double bonds in the intramolecular charge transfer transitions
Tethered 1,2-Si-Group Migrations in Radical-Mediated Ring Enlargements of Cyclic Alkoxysilanes: An EPR Spectroscopic and Computational Investigation
A 1,2-Dibromosilene: Generation, Spectroscopic Observation and Isomerization to a Silacyclohexane via Facile 1,2-Bromine Shift
A Pt(0) complex with cyclic (alkyl)(amino)silylene and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane ligands: synthesis, molecular structure, and catalytic hydrosilylation activity
Coordination-induced Hydrogen Abstraction in the Reactions of a Stable Dialkylphosphinyl Radical with BH3-Lewis Base Adducts
Global Exploration of Isomers and Isomerization Channels on the Quantum Chemical Potential Energy Surface of
H3CNO3
An Isolable Potassium Salt of a Borasilene-Chloride Adduct
Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene
Pentasila-1,4-diene: Homoconjugation between Si=Si Double Bonds via a SiMe2 Unit
A Dialkylsilylene-Pt(0) Complex with a DVTMS Ligand for the Catalytic Hydrosilylation of Functional Olefins
A Two-Coordinate Cyclic (Alkyl)(amino)silylene: Balancing Thermal Stability and Reactivity
A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene
Hydrogen Bonds-Enabled Design of a C1-Symmetric Chiral Brønsted Acid Catalyst
Ferrocenyl-substituted Bicyclo[1.1.1]pentasilanes: Evaluation of Significant Interactions between Ferrocenyl Units and Rigid Silicon Cages
Persistent four-coordinate iron-centered radical stabilized by π-donation
Wavy carbon: A new series of carbon structures explored by quantum chemical calculations
Recent Advances in η2-Disilene and η2-Disilyne Mononuclear Transition Metal Complexes and Related Compounds (For a special issue: Recent Developments in Organometallic Chemistry: 2016)
Persistent Dialkylsilanone Generated by Dehydrobromination of Dialkylbromosilanol
Prism-C2n Carbon Dimer, Trimer, and Nano-Sheets: A Quantum Chemical Study
Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives by photochemical cycloaddition of dialkylsilylene
Redox Reactions of a Stable Dialkylphosphinyl Radical
A Prism Carbon Molecule C20
Reactions of a Stable Phosphinyl Radical with Stable Aminoxyl Radicals
A heavy analogue of the smallest bridgehead alkene stabilized by a base
Two-coordinate Dialkylsilylene-Coinage Metal Complexes
Persistent Antimony- and Bismuth-Centered Radicals in Solution
Germanium-centered free radicals studied by muon spin spectroscopy
Isolable 2,3-Disila-1,3-butadiene via Double Sila-Peterson Reaction
Unexpected Formation of Highly Strained 2,5-Dioxa-Silabicyclo[2.1.0]Pentane by the Reaction of Isolable Dialkylsilylene with Benzil
Near-IR Absorbing Nickel(II) Porphyrinoids Prepared by Regioselective Insertion of Silylenes into Antiaromatic Nickel(II) Norcorrole
Palladium and Platinum η2-Disilyne Complexes Bearing an Isolable Dialkyldisilyne as a Ligand
Shintaro Ishida, Ryutaro Sugawara, Yoshifumi Misawa and Takeaki Iwamoto, Angew. Chem. Int. Ed., 2013, 52, 12869-12873. (DOI: 10.1002/anie.201308517)
Anthryl-substituted 3-Silylene-2-silaaziridine Obtained by Isomerization of Disilacyclopropanimine: An Exocyclic Silene Showing Distinct Intramolecular Charge Transfer Transition
Takeaki Iwamoto, Nobuyoshi Ohnishi, Naohiko Akasaka, Koichi Ohno, and Shintaro Ishida, J. Am. Chem. Soc., 135, 10606-10609.. (DOI: 10.1021/ja404045f)
New Isolable Dialkylsilylene and Its Isolable Dimer That Equilibrate in Solution
Takashi Abe, Ryoji Tanaka, Shintaro Ishida, Mitsuo Kira, and Takeaki Iwamoto, J. Am. Chem. Soc., 2012, 134, 20029-20032. (DOI: 10.1021/ja310391m)
A Two-Coordinate Palladium Complex with Two Dialkylphosphinyl Ligands
Takeaki Iwamoto, Fumiya Hirakawa, Shintaro Ishida, Angew. Chem. Int. Ed., 2012, 51, 12111-12114. (DOI: 10.1002/anie.201206997)
Siloxy-Substituted Cyclopentadiene Showing Aggregation-Enhanced Emission: An Application of Cycloaddition of Isolable Dialkylsilylene
Shintaro Ishida, Kenya Uchida, Tsunenobu Onodera, Hidetoshi Oikawa, Mitsuo Kira, Takeaki Iwamoto, Organometallics, 2012, 31, 5983-5985. (DOI:10.1021/om3005178)
Preparation of 4,7-Dibromobenzo[b]thiophene as a Versatile Building Block and Synthetic Application to a Bis(ethynylthienyl)oligoarene System
Persilastaffanes: Design, Synthesis, Structure, and Conjugation between Silicon Cages
Takeaki Iwamoto, Daisuke Tsushima, Eunsang Kwon, Shintaro Ishida, Hiroyuki Isobe, Angew. Chem. Int. Ed., 2012, 51, 2340-2344. (DOI:10.1002/anie.201106422, Press Release (2011 No.50))
Design of Chiral Bis-phosphoric Acid Catalyst Derived from (R)-3,3'-Di(2-hydroxy-3-arylphenyl)binaphthol: Catalytic Enantioselective Diels–Alder Reaction of α,β-Unsaturated Aldehydes with Amidodienes
A Stable Dialkylphosphinyl Radical
Shintaro Ishida, Fumiya Hirakawa, Takeaki Iwamoto, J. Am. Chem. Soc., 2011, 133(48), 12968-12971. (DOI:10.1021/ja205001m)
Addition of a Stable Dialkylsilylene to Carbon-carbon Unsaturated Bonds
Preparation of 1,4-Bis(2-ethynyl-3-thienyl) Benzene Derivatives Linked by Oligo(ethyleneglycol) Chain
Structure and Reactions of an Isolable Ge=Si Doubly Bonded Compound, Tetra(t-butyldimethylsilyl)germasilene
Chemistry of Bis(2-ethynyl-3-thienyl)arene and Related Systems, Part 5:Preparation of an Unsymmetrical 4,4'-Bis(3-thienyl)biphenyl Derivative Containing a 2-[2-(Diphenylphosphino)ethynyl]-3-thienyl Moiety
Synthesis and properties of 5,10,15,20-tetrakis[4-(alkoxysilyl)phenyl]porphyrins: an application of selective deprotection of benzaldehyde diethyl acetals in the presence of alkoxysilyl groups
Synthesis and Structures of (Dialkylsilylene)bis(phosphine)-nickel, Palladium, and Platinum Complexes and (η6-Arene)(dialkylsilylene)nickel Complexes
Reactions of an Isolable Dialkylsilylene with Ketones
An efficient and regioselective iodination of electron-rich aromatic compounds using N-chlorosuccinimide and sodium iodide
Synthesis and Structures of Deoxyribonucleoside Analogues for Triazole-linked DNA (TLDNA)
Synthesis and Facile Ring Expansion of Silylenecyclotetrasilane
Synthesis and Structure of Stable Base-Free Dialkylsilanimines
A Stable 1,2-Disilacyclohexene and Its 14-Electron Palladium(0) Complex
Chemistry of Bis(2-ethynyl-3-thienyl)arene and Related Systems. Part 7: "Preparation of 1,4-Bis(3-ethynylthieno[3,2-b]thiophen-2-yl)benzene Derivatives as Peptide-inspired Molecules,"
Unusual Bonding in Trisilaallene and Related Heavy Allenes
Chemistry of Bis(2-ethynyl-3-thienyl)arene and Related Systems. Part 6: "Preparation of 1,4-Bis(2-ethynyl-3-thienyl)benzene Derivatives Containing Fluorine Atoms at the 2,3- or 2,5-Positions of the Benzene Ring"
Chemistry of Bis(2-ethynyl-3-thienyl)arene and Related Systems. Part 5: "Preparation of an Unsymmetrical 4,4’-Di(3-thienyl)biphenyl Derivative Containing a 2-[2-(Diphenylphosphino)ethynyl]-3-thienyl Moiety"
Anthryl-Substituted Trialkyldisilene Showing Distinct Intramolecular Charge-Transfer Transition
Silicon Compounds with Inverted Geometry around Silicon Atoms (Highlight Review)
Multiple Bonds with Silicon: Recent Advances in Synthesis, Structure, and Functions of Stable Disilenes
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